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  4. Hydrogen peroxide solution 35% (perhydrol) canister 25 kg
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    Nadtlenek wodoru roztwór wodny 35% (perhydrol)

Hydrogen peroxide solution 35% (perhydrol) canister 25 kg

  • Kod produktu: A7025
  • Availability: Product available.
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  • 32.93 € 27.56 € 33.90 € gross
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    Parameters

    Hydrogen peroxide aqueous solution 35% (perhydrol)

    • Chemical formula: H2O2
    • CAS / EC / index number: 7722-84-1 / 231-765-0 / 008-003-00-9
    • Concentration: 35% (m/m), aqueous solution
    • Form / color / smell: colorless liquid, characteristic smell
    • Density (20 °C): approx. 1.13 g/cm³
    • pH (20 °C): 2–3
    • Molar mass (H2O2): 34.01 g/mol
    • Solubility: completely miscible with water
    • Freezing point (35%): approx. −33 °C
    • Boiling point (35%): ~108 °C (with decomposition)
    • Properties: strong oxidizer, corrosive; the solution may undergo slow decomposition (release of oxygen)
    • Packaging: HDPE canister with UN certification, DIN 61 cap, with seal and vent
    • Legal notes (EU): listed in Regulation (EU) 2019/1148 as a precursor to explosives – restrictions on trade for private users

    Characteristics and technological advantages

    Perhydrol (H2O2 35%) is a strong, oxygen-based oxidizer with a wide range of applications. Its action results from the controlled decomposition into water and oxygen, which means it does not leave foreign compounds in the process environment. The product is chlorine-free, does not introduce halides, and usually does not generate persistent by-products.

    In industrial practice, a 35% solution serves as a concentrated raw material, which – according to the safety data sheet and manufacturer’s instructions – is diluted to working levels appropriate for a given application. Below is an outline of the most common areas of use.

    Applications (industry overview)

    Food and beverage industry

    • Disinfection of packaging and aseptic lines: Hygiene of surfaces in contact with food (PET/HDPE, multilayer cartons, caps). After contact time and possible neutralization, residues decompose into H₂O and O₂.

    • CIP washing / biocidal rinsing of installations: Limiting biofilm and opportunistic microflora in dairies, breweries, juice plants.

    • Deodorization / oxidation of difficult organic deposits: In raw material preparation areas, waste logistics, and inter-process wastewater.

    Water and wastewater treatment

    • Odor removal: Oxidation of sulfides, mercaptans, and other odoriferous compounds in process waters and municipal/industrial wastewater.

    • Microbiological control of process water: Supporting disinfection – often in systems with UV or ozone to reduce reagent doses and by-products.

    • Advanced oxidation processes (AOP): H₂O₂ + UV/ozone/catalyst for the degradation of micro-pollutants and difficult-to-biodegrade compounds (e.g., phenols, aldehydes, traces of aromatic amines).

    Healthcare and professional hygiene

    • VHP (vaporized hydrogen peroxide): 35% H₂O₂ as a precursor for generating vaporized hydrogen peroxide for decontamination of cleanrooms, isolators, biosafety cabinets, and temperature-sensitive equipment.

    • Disinfection of surfaces and equipment: After preparing working solutions – wide spectrum of action (bacteria, viruses, spores). An alternative to chlorine agents, limiting the formation of chlorinated by-products.

    Pulp and paper industry

    • Bleaching of pulp and paper: Oxidizing bleaching without chlorine, reducing AOX load in wastewater.

    • Decolorization and bleaching of fibers: Cotton, viscose – preliminary stage before dyeing/finishing; control over fiber strength loss by optimizing pH, temperature, and stabilization.

    Maintenance and technical cleaning

    • Removal of deposits and organic discolorations: Protein-fat stains, soot, secondary discolorations from vegetable oils on compatible material substrates.

    • Biofilm reduction: An element of sanitary programs in processing and water installations (tanks, lines, coolers).

    Electronics and precision processes

    • Micro-etching / surface preparation: Component of baths for processing copper and alloys (PCB/EMS), usually in systems with mineral acids.

    • High purity washing: Component of formulations for decontaminating optical and metal components – necessary compatibility tests (aluminum, copper, brass, sinters).

    Laboratories, synthesis, and process chemistry

    • Auxiliary oxidizer: Reagent for selective oxidations, generating oxygen, supporting termination and cleaning reactions.

    • Neutralization of post-reaction contaminants: Oxidation of traces of sulfites, aldehydes, phenols, aromatic amines before directing the stream to purification.

    Agriculture and aquaculture (professional applications)

    • Hygienization of irrigation systems: Limiting biofilm and microbiological blockages in drip lines; protecting emitters and uniform distribution.

    • Disinfection of work surfaces and containers: Packing, sorting, greenhouse farms – as part of GHP/GMP.

    Environmental protection and health and safety

    • Odor detoxification and emergency neutralizations: Rapid reduction of odors at landfills, in pumping stations, and sedimentation tanks; supporting the decomposition of sulfur and nitrogen compounds with unpleasant odors.

    No consumer applications

    Perhydrol 35% is a professional product. It is not intended for retail/home use or for the independent preparation of consumer products.

    A concentration of 35% is a popular storage standard: it provides high stability and predictability of parameters, while being logistically convenient. It is easy to prepare working solutions with required concentrations for various technological lines.

    Work safety: 35% H2O2 is corrosive and strongly oxidizing – personal protective equipment (gloves, eye/face protection, clothing), compatible materials (HDPE, PTFE, acid-resistant steel under certain conditions), and ventilation are required. Avoid contact with catalytic metals, alkaline and organic reducing agents.

    How to use (example working dilutions)

    Prepare working solutions by slowly adding perhydrol to water (never the other way around), in a cool and well-ventilated place. Examples of calculations:

    • 1% H2O2 from 35%: 1 part perhydrol + 34 parts water (1:34).
    • 2%: 1 part + 16.5 parts water (≈1:16.5).
    • 3%: 1 part + 10.7 parts water (≈1:10.7).

    The choice of concentration, temperature, and contact time depends on the process/installation and should result from company procedures, industry standards, or equipment manufacturer documentation. After sanitizing surfaces that come into contact with food – always rinse with potable water.

    Product safety information Manufacturer information

    Product safety information

    Labeling according to Regulation (EC) No. 1272/2008 [CLP/GHS]

    HAZARD / Contains: hydrogen peroxide, aqueous solution

    GHS05 Corrosive substances icon

    Corrosive substances

    GHS07 Irritant substances icon

    Irritant substances

    Hazard statements:
    H302 Harmful if swallowed
    H315 Causes skin irritation
    H318 Causes serious eye damage
    H332 Harmful if inhaled
    H335 May cause respiratory irritation
    H412 Harmful to aquatic life with long lasting effects

    Precautionary statements:
    P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
    P264b Wash hands thoroughly after handling
    P273 Avoid release to the environment
    P280 Wear protective gloves/protective clothing/eye protection/face protection.
    P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water [or shower].
    P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    P312 Call a POISON CENTER/doctor if you feel unwell.
    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
    P310 Immediately call a POISON CENTER/doctor.
    P403+P233 Store in a well-ventilated place. Keep container tightly closed.
    • Other hazards
    • The substance does not meet the PBT or vPvB criteria according to Annex XIII of Regulation (EC) No 1907/2006.
    • This substance/mixture does not contain components considered to have endocrine disrupting properties to the environment, according to Article 57(f), Commission Regulation (EU) 2018/605 or the Commission Delegated Regulation (EU) 2017/2100.
    • This substance/mixture does not contain components considered to have endocrine disrupting properties to human health, according to Article 57(f) REACH, Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605, in concentrations of 0.1% or greater.

    Purchase of hydrogen peroxide 35% – legal information and requirements

     

    According to Regulation (EU) 2019/1148 of the European Parliament and of the Council, hydrogen peroxide at a concentration of 35% is a precursor of explosives subject to restrictions. The product may only be made available to:

    • professional users – entities purchasing and using the precursor solely for their own legitimate needs related to their professional activity (without further distribution),
    • economic operators – entities that make the precursor available to others (e.g., sell or distribute) in accordance with regulations.

    We do not sell to the general public (private individuals).

    What is required for purchase?

    • Download and complete the “Buyer’s Declaration” regarding the intended use (template available in the “Downloads” tab).
    • Fill it out in clear, printed letters, and sign (and stamp with a company seal if applicable).
    • Send a scan of the signed declaration to: sklep@apola.pl.

    Failure to send a correctly completed declaration will result in the cancellation of the order.

    Information regarding ADR transport:
    UN Number: UN 2014
    Proper shipping name UN: Hydrogen peroxide, aqueous solution
    Hazard class: 5.1 (oxidizing); additional hazard: 8 (corrosive)
    Packing group: II
    Environmental hazard: NO

    ADR Class 8 Corrosive materials icon ADR Oxidizing substances icon UN 2014 Hydrogen peroxide, aqueous solution icon
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